One of the correspondents for Comedy Central’s "Daily Show" has been tapped for a guest-starring role in the fourth season debut of NBC’s "Chuck" on Sept. 20, reports EW.com’s The Ausiello Files.

Olivia Munn will play a CIA agent who both teaches and intimidates Chuck and Morgan in the episode (and who happens to be "impossibly cool, smart and pretty"), the story says.

The same episode will feature a guest spot from "Rocky IV" star Dolph Lundgren, the article adds.